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New FM2N paper by M. Boudard et L. Rapenne

Published on April 3, 2016
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Communique from March 25, 2016 to March 31, 2016

The paper "One-step process to form a nickel-based/carbon nanofoam composite supercapacitor electrode using Na2SO4 as an eco-friendly electrolyte" has been published in RSC Advances.

You will find  here the paper by Michel Boudard  & Laetitia Rappenne. Abstract:
"In this work, NiOx is anodically electrodeposited onto carbon nanofoam (CNF) to form a composite electrode devoted to supercapacitor applications. The use of NiSO4 as precursor in electrodeposition results in the formation of NiO and NiOOH species, as confirmed by XPS analysis, by means of a one-step anodic process. The presence of both NiO and NiOOH suggests the existence of pseudocapacitance, as observed in MnO2 and RuO2 materials. By employing Na2SO4, an eco-friendly electrolyte, the resulting composite delivers a specific capacitance of 150 F g−1 at 1 A g−1 considering the total mass of the electrode (deposit plus substrate). In addition, this composite electrode can operate in a very broad potential window, as high as 2.2 V, suggesting its application in high energy density electrochemical supercapacitors.In this work, NiOx is anodically electrodeposited onto carbon nanofoam (CNF) to form a composite electrode devoted to supercapacitor applications. The use of NiSO4 as precursor in electrodeposition results in the formation of NiO and NiOOH species, as confirmed by XPS analysis, by means of a one-step anodic process. The presence of both NiO and NiOOH suggests the existence of pseudocapacitance, as observed in MnO2 and RuO2 materials. By employing Na2SO4, an eco-friendly electrolyte, the resulting composite delivers a specific capacitance of 150 F g−1 at 1 A g−1 considering the total mass of the electrode (deposit plus substrate). In addition, this composite electrode can operate in a very broad potential window, as high as 2.2 V, suggesting its application in high energy density electrochemical supercapacitors."

DOI: 10.1039/C5RA22046G/

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Date of update April 3, 2016

Univ. Grenoble Alpes